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Table 2 Prominent IR Raman spectral bands observed in AH3 and AH7 (ν cm-1)

From: Studies on the synthesis, characterization, binding with DNA and activities of two cis-planaramineplatinum(II) complexes of the form: cis-PtL(NH3)Cl2 where L = 3-hydroxypyridine and 2,3-diaminopyridine

 

IR (cm-1)

Raman

AH3

3309 (s, NH and OH), 3062 (w, CH), 1649(w, NH), 1595 (s, 'aromatic ring'), 1444 (s, 'aromatic ring'), 1281 (s, OH), 1213 (w, CO), 1105 (w, CO), 1028 (ring stretch), 798 (m, CH), 687 (m, CH), 580 (w, Pt-N), 546 (m, Pt-N), 514 (m, Pt-N), 432 (m, pyridine ring)

3076 (m, NH), 2467 (m br, CH) 1603 (w, NH), 1030 (s, CH), 866 (m, CH), 664 (w, pyridine ring), 519 (w, Pt-N(NH3)), 330 (m, Pt-N(3-hydroxypyridine)), 243 (w, Pt-N(2-hydroxypyridine)), 122 (s, Pt-N), 81 (m, lattice)

AH7

3192 (s br, NH and CH stretch), 1614 (m, NH bending), 1539 (s, aromatic ring stretch), 1371 (m, CH bending), 1302 (s, ring in-plane deformation), 1211 (m, CH in-plane bending of heterocyclic ring), 777 (w d, ring out-of-plane deformation), 496 (w, Pt-N stretch)

3562 (w, NH stretch), 3314 (s, NH stretch), 2806 (m, CH stretch), 2361 (m, ring stretch), 1537 (m, NH bending), 1030 (s, CH in-plane bending), 797 (m, ring out-of-plane deformation), 346 (m, Pt-Cl stretch), 95 (m, ring bending)

  1. The letters 's', 'm', 'w', 'd' and 'br' stand for 'strong', 'medium', 'weak', 'doublet' and 'broad' respectively.